Influence of metal ions on thermal generation of carbohydrate radicals in native and modified starch studied by EPR

Maria Łabanowska , Małgorzata Kurdziel , Ewa Bidzińska , Teresa Fortuna , Sławomir Pietrzyk , Izabela Przetaczek-Rożnowska , Jacek Rożnowski

Abstract

Influence of enrichment with ions from alkali (K), alkali-earth (Mg) and d transition (Cu, Fe) metal groups of native and modified starches on the process of carbohydrate radicals generation has been studied using electron paramagnetic resonance (EPR) spectroscopy. This technique allows following the character and amount of created radicals, as well as the changes in coordination sphere of transition metal ions incorporated into starch matrix. The main difference between transition metal ions and the ions of alkali and alkali-earth metals consisted in the character of their interactions with functional groups of starch. Transition metal ions coordinated glucose units of starch and influenced the mechanism of carbohydrate radical formation independently of the kind of starch modification. Interaction of starch, native and modified, with ions of alkali and alkali-earth metals did not change the mechanism of radical generation, however, influenced their number. Contents of total metal ions found analytically by spectroscopic methods and by EPR allowed determination of the amount of transition metal ions engaged in interactions with starch matrix, as well as the differentiating of native and modified starch in respect of their metal ions adsorptive ability.
Author Maria Łabanowska
Maria Łabanowska,,
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, Małgorzata Kurdziel
Małgorzata Kurdziel,,
-
, Ewa Bidzińska
Ewa Bidzińska,,
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, Teresa Fortuna (FoFT / DoAaEFQ)
Teresa Fortuna,,
- Department of Analysis and Evaluation Food Quality
, Sławomir Pietrzyk (FoFT / DoAaEFQ)
Sławomir Pietrzyk,,
- Department of Analysis and Evaluation Food Quality
, Izabela Przetaczek-Rożnowska (FoFT / DoAaEFQ)
Izabela Przetaczek-Rożnowska,,
- Department of Analysis and Evaluation Food Quality
, Jacek Rożnowski (FoFT / DoAaEFQ)
Jacek Rożnowski,,
- Department of Analysis and Evaluation Food Quality
Journal seriesStarch-Starke, ISSN 0038-9056, (A 25 pkt)
Issue year2013
Vol65
No5-6
Pages469-482
Publication size in sheets0.65
Keywords in Englishcarbohydrate radicals, electron paramagnetic resonance, metal ions, starch modifications
DOIDOI:10.1002/star.201200165
URL http://onlinelibrary.wiley.com/doi/10.1002/star.201200165/epdf
Internal identifierWTŻ/2013/97
Languageen angielski
Score (nominal)25
ScoreMinisterial score = 25.0, 26-07-2017, ArticleFromJournal
Ministerial score (2013-2016) = 25.0, 26-07-2017, ArticleFromJournal
Publication indicators WoS Citations = 19
Citation count*11 (2016-09-12)
Additional fields
FinansowanieThis work was partly supported by grant NN 312 43 80 37.
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