Pyrazoline-based colorimetric and fluorescent probe for detection of sulphite

Tomasz Uchacz , Gabriela Jajko , Andrzej Danel , Paweł Szlachcic , Szczepan Zapotoczny

Abstract

Two pyrazoline-based fluorescent and colorimetric probes have been synthesized and their photophysical properties have been investigated by means of electronic absorption and emission spectroscopy. The compounds differ from each other by the presence of a phenyl or thiophene end group attached to the α,β-unsaturated ketone. The probes detect sulphite anions in the Michael addition reaction to the α,β-unsaturated ketone with a high selectivity and good sensitivity (7.56 μM for phenyl and 4.87 μM for the thiophene counterpart). Here, the optical response is based on the recovery of triphenylpyrazoline fluorescence, which is largely blue-shifted as compared to weak charge transfer emission of the sensors. This large hypsochromic shift of the emission maximum along with a strong fluorescence enhancement (up to Isulphite/I0 = 43) can be an advantage in terms of the accurate evaluation of the fluorescence intensity ratio. The pyrazoline-based sensor decorated with thiophene is able to detect sulphite species in river water solutions with a good selectivity and sensitivity.
Author Tomasz Uchacz
Tomasz Uchacz,,
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, Gabriela Jajko
Gabriela Jajko,,
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, Andrzej Danel (FoFT / IoCh)
Andrzej Danel,,
- Institute of chemistry
, Paweł Szlachcic (FoFT / IoCh)
Paweł Szlachcic,,
- Institute of chemistry
, Szczepan Zapotoczny
Szczepan Zapotoczny,,
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Journal seriesNew Journal of Chemistry, ISSN 1144-0546, e-ISSN 1369-9261, (N/A 70 pkt)
Issue year2019
No43
Pages874-883
Publication size in sheets0.5
ASJC Classification1503 Catalysis; 1600 General Chemistry; 2505 Materials Chemistry
DOIDOI:10.1039/C8NJ05017A
URL https://pubs.rsc.org/en/content/articlelanding/2019/nj/c8nj05017a#!divAbstract
Internal identifierWTŻ/2019/15
Languageen angielski
Score (nominal)70
Score sourcejournalList
Publication indicators WoS Citations = 3; Scopus SNIP (Source Normalised Impact per Paper): 2016 = 0.766; WoS Impact Factor: 2018 = 3.069 (2) - 2018=3.038 (5)
Citation count*6 (2020-03-31)
Additional fields
Finansowaniecontract no. POIG.02.01.00-12-023/08, DS 3711/ICh/2017, grant number: TEAM/2016-1/9
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* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perish system.
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